Queen Chrysalis and Princess Cadence from MLP :FIM. I was listening to the song "This Day Aria" and just had to draw them. Then I was like "huh, I want to try to draw Chrysalis in human form!". That is how this formed. Then I decided to draw the Mane 6, Luna, and Celestia in human forms as well. They will be posted today/tomorrow (depending on your time zone).
I like how Chrysalis came out, but not so much Cadence. I'll have to work on that.
Queen Chrysalis and Princess Cadence (c) Hasbro